p₁V₁^κ = p₂V₂^κ · compression and expansion

In an adiabatic process there is no heat exchange with the surroundings: p·V^κ = const. Compressing the gas does work on it, which raises its temperature (that is why a bicycle pump warms up).
An adiabatic process takes place with no heat exchange with the surroundings (Q = 0) — for example during rapid compression or expansion of a gas. It is governed by the equation:
where is the adiabatic index (1.4 for a diatomic gas such as air, 1.67 for a monatomic one). The temperature changes according to .
The effect: compressing a gas adiabatically warms it up (the work turns into internal energy — which is why a bicycle pump heats up), and expanding it cools it down (the principle behind refrigerators and the formation of clouds).
Because we do work on it, and with no heat exchange all of that energy raises the internal energy of the gas — that is, its temperature. Hence the warm pump and the hot air in a diesel engine.
On an isotherm the temperature is constant (the gas exchanges heat) and p·V = const. On an adiabat there is no heat, so the temperature changes and p·V^κ = const — the adiabat falls more steeply than the isotherm.
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