A nucleus's mass is smaller than the sum of the masses of the nucleons that make it up — this shortfall is the mass defect Δm, and the corresponding binding energy is E=Δm·c². Binding energy per nucleon peaks for nuclei with a mass near iron's (Fe-56), which is why they are the most stable. Change the mass number A and watch the curve.

I'll give you a target binding energy per nucleon — pick the mass number A so the point on the curve reaches it.
What is mass defect?
A nucleus's mass is smaller than the sum of the masses of the free protons and neutrons that make it up. This missing piece of mass is the mass defect . It vanished because energy was released when the nucleons were bound together — and energy has mass.
Invariant — binding energy:
Binding energy is the energy you must supply to pull a nucleus apart into separate nucleons — and it equals exactly the mass defect times . Dividing by the number of nucleons gives — a measure of how tightly a single nucleon is held.
Why is Fe-56 the most stable?
The curve climbs steeply for light nuclei, reaches a peak at A ≈ 56 (iron, ~8.8 MeV per nucleon), then slowly falls. The top = the largest binding energy per nucleon = the most tightly bound, most stable nucleus. All other nuclei "want" to move toward this peak.
Where does nuclear energy come from?
From the binding-energy difference. Fusion of light nuclei (the Sun) and fission of heavy ones (a reactor) — both shift nuclei toward Fe-56, into a region of higher . The surplus binding energy is released as the reaction's energy.
Why you need this for the exam:
Nuclear problems almost always come down to : compute the mass defect (sum of nucleon masses minus the nuclear mass), multiply by . And the shape of the curve, with its maximum at iron, explains why the Sun shines and a reactor works.
Remember: a nucleus's mass < the sum of nucleon masses, and that difference is the binding energy: . The peak of the curve at Fe-56 is the most stable nucleus in the Universe.
A nucleus's mass is smaller than the sum of the masses of the nucleons that make it up. This missing piece is the mass defect:
The mass defect corresponds to the binding energy (Einstein's formula): This is the energy you must supply to pull the nucleus apart into free nucleons.
Stability is governed by the binding energy per single nucleon: It reaches a maximum for nuclei with a mass close to iron (-56) — which is why they are the most stable.
Symbols: — mass defect, — number of protons, — number of neutrons, — masses of the proton and the neutron, — mass of the nucleus, — mass number, — binding energy, .
The difference between the sum of the nucleon masses and the actual (smaller) mass of the nucleus. It corresponds to the binding energy: E=Δm·c².
Because it has the largest binding energy per nucleon — its nucleons are bound most tightly, so splitting or fusing such a nucleus no longer releases energy.
From the difference in binding energy: when the reaction products are closer to the peak of the curve than the reactants, the excess energy is released (E=Δm·c²).
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